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Beilstein J. Org. Chem. 2018, 14, 3047–3058, doi:10.3762/bjoc.14.283
Graphical Abstract
Scheme 1: Degenerative radical transfer of xanthates to olefins.
Scheme 2: Photocatalytic RAFT polymerization of xanthate 4.
Figure 1: Photoluminescence (PL) spectra of the 3MLCT state of 8 in degassed DMSO solvent with (A) various co...
Figure 2: (A) ns-Transient absorption spectra of photocatalyst 8 in degassed DMSO recorded at different delay...
Figure 3: UV–vis absorption spectrum of 1a (1 mM solution in DMSO).
Scheme 3: Determination of quantum yield.
Scheme 4: Proposed reaction mechanism.
Beilstein J. Org. Chem. 2015, 11, 1933–1943, doi:10.3762/bjoc.11.209
Scheme 1: Generation of iminyl radicals from oxime derivatives.
Scheme 2: Oxidative generation of iminyl radicals from N–H ketimines.
Scheme 3: Copper-catalyzed aerobic reactions of in situ generated biaryl N–H ketimines.
Scheme 4: Copper-catalyzed aerobic C–C bond cleavage reactions of N–H ketimines.
Scheme 5: Proposed reaction mechanisms for the formation of 3a, 4a and 5a, and the reaction of hydroperoxide 6...
Scheme 6: Formation of bromoketone 6e.
Scheme 7: Electrophilic cyanation of Grignard reagents with pivalonitrile (1f).
Scheme 8: Electrophilic cyanation with pivalonitrile (1e).
Beilstein J. Org. Chem. 2013, 9, 1217–1225, doi:10.3762/bjoc.9.138
Scheme 1: Aliphatic C–H oxidation with amidines and ketimines by 1,5-H radical shift.
Scheme 2: Aliphatic C–H oxidation with hydroperoxides.
Scheme 3: Proposed reaction mechanisms for the formation of 2a, 3a, and 4a.
Scheme 4: Proposed reaction mechanisms for the formation of 5 and 6.
Scheme 5: The reaction of secondary hydroperoxide 1o.
Scheme 6: 1,4-Dioxygenation of alkanes.
Scheme 7: Aerobic 1,4-dioxygenation of alkanes in the CuCl–NHPI catalytic system.